Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen. It can occur when carbonsteel equipment becomes exposed to wet h 2 s service environments, and it can come in several different forms. Corrosion of steels in sour gas environments international nuclear. The presence of co2 in solution does not affect the fracture mechanism. Wet h 2 s corrosion can be a particularly dangerous form of corrosion because damage caused by it takes place on the interior of.
Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. The effect of plastic strain on sulfide stress cracking. Thorough understanding of scc mechanisms of dss in chloride and hydrogen sulfidecontaining solutions has been useful for material selection in many. A method for testing pipe steels under the conditions of. Sulfide stress cracking ssc vs hydrogen induced cracking. The resistance to chlorideinduced stress corrosion cracking of uns n08031 was tested on ubend specimens according to astm g 30 for a testing time of 2000 hours. Reliability of dissimilar metal welds subjected to sulfide. The stress corrosion cracking behaviour of uns n08031 in. H2s and hydrogen attackcorrosion refining, hydrocarbons. The variation of the name is due to the lack of agreement in the mechanism of failure.
Standard material requirements sulfide stress cracking. Reliability of dissimilar metal welds subjected to sulfide stress cracking vol. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. It is a progressive type of failure that produces cracking at stress levels that are well below the materials tensile strength. Tib and mncrmo was evaluated using constant load tensile test. Sulfide stress crackingnace mr01752002, mr0175iso 15156 651 te c h n i c a l new sulfide stress cracking standard for refineries don bush, principal engineer materials, at emerson process management fisher valves, is a member and former chair of a nace task group that has written a document for refinery applications, nace mr0103. H2s partial pressure, 1 mpa and co2 partial pressure, 1 mpa. The blistering damage tends to form parallel to the surface and to the direction of hoop stress.
Other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. The mechanism of stressrelief cracking in a ferritic. The cracking resistance begins to deteriorate when fresh martensite exceeds 5 vol%. Rotten eggs gas and inflammation in arthritic joints. Apart from sscc, h2s also cause other cracking, including stress corrosion cracking, hydrogeninduced cracking and stepwise cracking, stressoriented hydrogen induced cracking, soft zone cracking and galvanically induced hydrogen stress cracking. The manuscript can be downloaded following this link or directly.
Sulfide stress cracking of nickelcontaining lowalloy steels. Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Stress corrosion cracking an overview sciencedirect topics. Sulfide stress cracking an overview sciencedirect topics. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6.
Stressrelief cracking src is a major cause of weld failures in creep resistant, precipitation strengthened materials, such as ferritic steels, stainless steels, and nibased super alloys. As a form of hydrogen stress cracking, ssc is a cracking mechanism in pipelines, facilities piping and any equipment that comes in contact with sour wet h2s service conditions. The critical stress intensity factor for sulfide stress cracking, kissc, k issc of fully martensitic microstructures tempered to strength levels in the 620 to 725mpa range were 56 and 40mpam 12, whereas fully tempered bainitic microstructures with similar ys gave k issc values between 42 and 32mpam 12 garber, 1983. This article discusses catastrophic brittle fracture mechanisms due to eac. There are maximum acceptable h 2 s concentration limits in sale quality oil and gas, which require. Sulfide stress corrosion cracking resistance was evaluated as per nace tm017796 method a using cylindrical test piece and a load ring. Hydrogen induced cracking of low strength steels in. Large manganese sulphides were found in metallographic specimens not initiating any cracks. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Which alloy is for sulfide stress and stress corrosion. We published this article under an openaccess license. These tests were carried out on specimens, which were pretreated under the following conditions for 168 hours. Partial pressure of the h 2 s is determined by multiplying the mole fraction of h 2 s in the gas by the total pressure. Recent experience has demonstrated the risk of sscc and hic, sometimes known as hydrogen embrittlement he, of low strength steels subject to high residual stress derived from fabrication techniques.
Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. As described above, numerous theories exist on the causes of stressrelief cracking and these theories may all be valid under certain circumstances. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. Subsequent improvements in the metallurgy of steels for highpressure gas and oil wells and improved selection methods for highstrength alloys have been based on laboratory test methods.
The major hazards of h 2 s are its ability to cause rapid damage to health or sudden death due to accidental exposure and metal integrity failure due to general corrosion or cracking. Standard material requirements sulfide stress cracking resistant metallic materials for oilfield equipment contents 1. This phenomenon is generally termed sulfide stress cracking ssc 1 when operating at room temperature and stress corrosion cracking scc1 when operating at higher temperatures. Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and sulfide stresscorrosion cracking. The cracking usually occurs in the heataffected zone, which is the most susceptible area for crack initiation, due to solidstate metallurgical reactions during both heating and cooling thermal cycles. The lattice diffusion of hydrogen is decreased by the addition of ni, whereas the subsurface hydrogen concentration remains constant in 5% nacl solution and decreases in nace tm0177 solution up to 5% ni. In recognition of the variation with temperature and with different materials this phenomenon is here called environmental cracking ec. Hydrogen sulfide stress corrosion cracking in materials.
The slow strain rate stress corrosion cracking testa 50 year. The values ofk issc are determined for various casing tubes made of different types of steel after heat treatment. Theories of hydrogenrelated cracking mechanisms are outlined with emphasis placed on sulphide stress cracking and hydrogen induced cracking in carbon and. Processes or conditions involving wet hydrogen sulfide, i. Link to corrigendum together with my colleagues and good friends dr. The article also introduces a quantitative criterion to determine the maximum allowable defect size based on fracture mechanics principles. A study on the mechanism of stress corrosion cracking of. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. This paper analyzed the hsla pipeline steels stress corrosion behavior and mechanism which tested in the saturated solution of h2s.
Field history the production unit is installed as close to the oil wells as possible and is used to separate gas and water from the crude oil. Environmentally assisted cracking of drill pipes in. Pdf thanks to their high corrosion resistance, super martensitic stainless steels are commonly used in the oil and gas industry, particularly in sour. The mechanism of sulfide stress cracking involves a combination of stress corrosion cracking and hydrogen embrittlement. Basics of sulfide stress cracking ssc and stress corrosion cracking scc ssc and scc are cracking processes that develop in the presence of water, corrosion and surface tensile stress. Standard test method laboratory testing of metals for. Pdf stress corrosion cracking of 2205 duplex stainless steel in h 2. However, the paint on the metal only retards the initiation of corrosion and still, even. In that article, we concluded that while localized corrosion appears to be a prerequisite for anodic eac modes such as stress corrosion cracking scc, hydrogenassisted eac mechanisms like hydrogen stress cracking hsc are exacerbated at cathodic potentials. Variation and degradation of p110 casing steel mechanical properties, due to sulfide stress cracking ssc in sour environments, was investigated using tensile and impact tests. Strain and sulfide stress cracking in pipeline girth welds. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. H 2 s can cause corrosion of stainless steels such as 316 and 410 stainless in the form of sulfide stress cracking. Wet hydrogen sulfide h2s cracking inspectioneering.
To check its resistance to scc and ssc, several tests were performed. The mechanism of sulfide stress cracking involves a combination of stress. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. In a previous post, we discussed the broad differences between anodic and cathodic forms of environmentally assisted cracking eac. Alloys which are commercially available and those which have modified metallurgical structures and. This article is reporting the sulfide stress cracking of stainless steel 410 in annealed condition. This article describes current industry practices to catalog features observed after sulfide stress cracking testing. Mechanism of stress relief cracking in a granular bainitic. We propose a testing method for the evaluation of the threshold crack resistancek issc of pipe steels under the conditions of sulfide stress corrosion cracking. Sulfide stress cracking of nickelcontaining lowalloy. Sulfide stress corrosion cracking and hydrogen induced. A tensile stress higher than the threshold stress, frequently including some dynamic or cyclic component to the stress.
In other words, it can support a stress of 80,000 psi with an elongation of less than 0. The use of dss has been restricted in some cases because of stress corrosion cracking scc, which can initiate and grow in either the ferrite or austenite phase depending on the environment. Figure 41 three conditions necessary for scc scc cracking is usually oriented longitudinally in response to the hoop stress of the pipe, which is. Sulfide stress cracking of stainless steel 410 in sour. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Which alloy is best to resist sulfide stress cracking and stress corrosion cracking.
The effect of cold work and strain ageing on the sulfide stress cracking resistance and mechanical properties of expanded tubular steels a laboratory study. Sulfide stress cracking nace mr01752002, mr0175iso. Many changes have been made with austenitic stainless steels. The authors conducted extensive analyses to explore the effects of metallurgical factors on the resistance of line pipe steels to hydrogen induced cracking hic and sulfide stress cracking ssc. When sulfides are present in caustic solutions the scc has been reported to occur at lower temperatures. Pdf sulfide stress corrosion cracking and hydrogen. However, it has now been shown to be present naturally in our bodies and reside in. Sulfide stress cracking ssc along with hydrogen embrittlement he prevents the use of less expensive high strength carbon steel alloys in the recovery of fossil fuels in h2s containing sour service environments that are commonly seen in deep well fossil fuel recovery efforts. Hydrogen sulfide is a gas more commonly associated with the smell of rotten eggs and blocked drains. The general reasons for stressrelief cracking are known, but the underlying mechanisms are still a source of debate. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Most of the published work is limited to strains less than 0.
The mechanism of stressrelief cracking in the coarsegrained heataffected zone cghaz of a material can be investigated through stressrelaxation. Pdf sulfide stress corrosion study of a super martensitic stainless. An industry value that has been developed is nace mr01. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved. To our surprise, it was not true in the studied case. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack growth rates associated with stress corrosion to. Ssc is one of the many environmental cracking mechanisms resulting in pipeline steels exposed to aqueous sour service environments. Hydrogen embrittlement is a function of the hydrogen absorption characteristics of the metal in the aggressive environment, which is the formation of molecular hydrogen from atomic hydrogen within the metal structure 160. Sulfide stress cracking is the cracking of a metal under the combined action. Sulfide stress cracking ssc is just one of several forms of hydrogen. The applied stress was 70% and 100% of the yield strength ys of the material.
Sulphide stress cracking ssc is the biggest concern 9. It should not be confused with the term stress corrosion cracking which is an anodic. Hydrogen induced cracking and sulphide stress cracking of carbonmanganese steels 517 introduction, sulphide inclusions are considered as the most dangerous sites for hic initiation. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. Sulfide stress cracking ssc resistance of casing steels with different alloying chemistries i. The letter in conjunction with the number designates parameters such as the maximum yield strength and the minimum ultimate strength which for l80 pipe are 95,000 psi. Pdf stress corrosion cracking scc behavior of 2205 duplex stainless steel dss in h2sco2. Hydrogen induced cracking and sulphide stress cracking of. Used sem observed the fracture, and then the steels corrosion rate and shortterm corrosion behavior were analyzed by electrochemical polarization. Sulfide stress cracking nace mr01752002, mr0175iso 15156. Is sulfide stress cracking an anodic or a cathodic process.
Although the general causes of stressrelief cracking are known, different metals or alloys exhibit different types of stress relief mechanisms, but the general underlying mechanisms still unknown. Ssc is a form of spontaneous brittle breakdown in occurring in highstrength. Sulfide stress cracking, a form of hydrogen embrittlement, first became a serious problem in the oil industry in 1951. Corrosion fatigue cf, hydrogen induced cracking hic and sulfide stress cracking ssc. The history of dynamic straining in stress corrosion cracking studies and the evolution of the slow strain rate. Corrosionpedia what is sulfide stress cracking ssc.